An Sr doping 0.65(Bi0.5Na0.5) TiO3-0.35 (Sr0.7+x + Bi0.2) TiO3 ceramic with tunable crystal structures and energy storage performances

نویسندگان

چکیده

A group of 0.65(Bi0.5Na0.5)TiO3 -0.35(Sr0.7+x + Bi0.2)TiO3 (BNT-S0.7+xBT) composite ceramic pellets are synthesized using a traditional solid sintering method, where tunable x, the changeable volume Sr, is to tailor energy storage through adjustments A-site stoichiometry in BNT-S0.7+xBT. We find that small excess Sr2+ ions will result an extensively tuning on crystal grain size and even contribute disorder charge fluctuation As such, BNT-S0.7+xBT exhibits minimum average highly compact morphology, thus, BNT-S0.75BT high dielectric constant (?r) about 5100 at 110 °C. Meanwhile, relatively thin polarization–electric field (P–E) loop with maximum polarization 42 ?C/cm2 low remnant electric 5 obtained pellet under 100 kV/cm, corresponding density 0.98 J cm?3 good ? 70.7%. Attractively, (Pm) 25–100 °C hardly decreases, implying excellent temperature stability performances which favors relaxor ferroelectric ceramics valuable supercapacitor serving evaluated temperature.

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ژورنال

عنوان ژورنال: Journal of Materials Science: Materials in Electronics

سال: 2021

ISSN: ['1573-482X', '0957-4522']

DOI: https://doi.org/10.1007/s10854-021-05842-5